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    PracticeAQA GCSEAQA GCSE Chemistry Higher Tier Paper 2Question 05.1
    Medium2 marksStructured
    Chemistry of the atmosphereHigheratmospheric chemistrycombustionpollutants

    AQA GCSE · Question 05.1 · Chemistry of the atmosphere

    Table 2Natural gasHydrogenFuelEnergy released in kJ11.937.1Mass of carbon dioxideproduced in grams0.001.83Mass of water vapourproduced in grams0.751.50Mass of oxides of nitrogenproduced in grams6.6 × 10⁻⁴4.9 × 10⁻⁴

    This question is about burning fuels in central heating boilers. In the future, gas central heating boilers may burn hydrogen rather than natural gas. Table 2 shows information about these fuels when 1 dm³ of the fuel is burned in a central heating boiler.

    Explain how oxides of nitrogen are produced when burning fuels.

    How to approach this question

    The question asks how oxides of nitrogen (NOx) are formed during combustion. 1. Think about what is present during combustion in a boiler. There is the fuel and there is air. 2. What are the main gases in the air? 3. The fuel itself doesn't contain nitrogen. So where does the nitrogen for the oxides of nitrogen come from? 4. What condition inside a boiler or engine allows these normally unreactive gases from the air to react?

    Full Answer

    At the high temperatures and pressures found inside an engine or boiler, nitrogen and oxygen from the air react together to form oxides of nitrogen (like NO and NO₂).
    Oxides of nitrogen, often abbreviated as NOx (e.g., NO, NO₂), are atmospheric pollutants. They are not typically formed from the fuel itself, but from the air used in the combustion process. Air is approximately 78% nitrogen (N₂) and 21% oxygen (O₂). Normally, nitrogen is a very unreactive gas due to the strong triple bond in the N₂ molecule. However, the very high temperatures and pressures inside a combustion engine or a central heating boiler provide enough energy to break these strong bonds. This allows nitrogen and oxygen from the air to react with each other, forming various oxides of nitrogen.

    Common mistakes

    ✗ Stating that the nitrogen comes from the fuel. ✗ Forgetting to mention the essential condition of high temperature. ✗ Just saying "from the air" without specifying which gases from the air react.
    Question 04.6All questionsQuestion 05.2

    Practice the full AQA GCSE Chemistry Higher Tier Paper 2

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