Medium2 marksMultiple Choice
AQA GCSE · Question 08.4 · Chemical analysis
Flame emission spectroscopy is used to identify metal ions in a firework. Figure 8 shows the flame emission spectra of five individual metal ions and a spectrum for a mixture of two metal ions. Which two metal ions are in the mixture? Select two options.
Flame emission spectroscopy is used to identify metal ions in a firework. Figure 8 shows the flame emission spectra of five individual metal ions and a spectrum for a mixture of two metal ions. Which two metal ions are in the mixture? Select two options.
Answer options:
A.
Ca²⁺
B.
Cu²⁺
C.
K⁺
D.
Li⁺
E.
Na⁺
How to approach this question
1. Look at the spectrum for the "Mixture". It has several black lines at specific positions.
2. Compare the pattern of lines in the mixture with the pattern for each individual metal ion (Ca²⁺, Cu²⁺, etc.).
3. Go through the ions one by one. For an ion to be in the mixture, ALL of its characteristic lines must appear in the mixture's spectrum at the exact same positions.
4. Identify the two ions whose complete line patterns are found within the mixture's spectrum.
Full Answer
Li⁺, Na⁺
To identify the ions in the mixture, we need to find which individual spectra, when combined, create the mixture spectrum. Each line in an individual spectrum is like a fingerprint for that ion.
- **Compare Li⁺ with the mixture:** The Li⁺ spectrum has lines at positions 100, 220, and 300-315. All of these lines are present in the mixture spectrum. So, Li⁺ is in the mixture.
- **Compare Na⁺ with the mixture:** The Na⁺ spectrum has one thick line at position 260-270. This line is also present in the mixture spectrum. So, Na⁺ is in the mixture.
- **Check the others:** The lines for Ca²⁺, Cu²⁺, and K⁺ do not match the lines seen in the mixture.
Therefore, the mixture contains Li⁺ and Na⁺.
Common mistakes
✗ Choosing an ion just because one of its lines matches. ALL lines must match.
✗ Guessing without carefully comparing the line positions.
✗ Only selecting one of the two correct ions.
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