Medium2 marksStructured
AQA GCSE · Question 10.2 · The rate and extent of chemical change
Give the approximate temperature and pressure used in the reactor.
Give the approximate temperature and pressure used in the reactor.
How to approach this question
Recall the specific compromise conditions used for the Haber process.
1. **Temperature:** Is a high or low temperature favoured for the forward reaction (which is exothermic)? Is a high or low temperature needed for a fast rate? What compromise is reached?
2. **Pressure:** Is a high or low pressure favoured for the forward reaction (which has fewer moles of gas)? What are the practical and economic limits on pressure? What compromise is reached?
Full Answer
Temperature: 450 °C
Pressure: 200 atmospheres
The Haber process conditions are a compromise between reaction rate, equilibrium yield, and cost.
- **Temperature: 450 °C.** The forward reaction (N₂ + 3H₂ ⇌ 2NH₃) is exothermic. According to Le Chatelier's principle, a low temperature would favour a high yield of ammonia. However, a low temperature would also mean a very slow rate of reaction. A high temperature increases the rate but lowers the yield. 450 °C is a compromise temperature that gives a reasonable rate and a manageable yield, especially when used with an iron catalyst.
- **Pressure: 200 atmospheres (atm).** The forward reaction involves a decrease in the number of moles of gas (from 4 moles of reactants to 2 moles of product). According to Le Chatelier's principle, a high pressure would favour a high yield of ammonia. However, building and maintaining very high-pressure equipment is expensive and dangerous. 200 atm is a compromise pressure that gives a good yield without being excessively costly.
Common mistakes
✗ Getting the numbers wrong.
✗ Mixing up the units (e.g., °C for pressure).
✗ Suggesting extremely high or low values.
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