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Atomic structure and the periodic tableHigheratomic structureisotopesdefinition

AQA GCSE · Question 03.3 · Atomic structure and the periodic table

Chadwick's experiments showed the existence of neutrons in an atom.
This led to an understanding of isotopes.
Define the term 'isotopes'.
Refer to subatomic particles in your answer.

How to approach this question

The definition of isotopes has two parts. 1. What is the same about atoms of the same element? Which subatomic particle defines an element? 2. What is different about isotopes of that element? Which subatomic particle's number can vary?

Full Answer

Isotopes are atoms of the same element (so they have the same number of protons) but with a different number of neutrons.
Isotopes are defined as atoms that have the same number of protons but a different number of neutrons. - **Same number of protons:** The number of protons (the atomic number) determines which element an atom is. Since isotopes are atoms of the same element, they must have the same number of protons. - **Different number of neutrons:** The variation in the number of neutrons leads to a different mass number for each isotope, but it does not change the chemical properties, which are determined by the electron configuration (and thus the number of protons). For example, Carbon-12 has 6 protons and 6 neutrons, while Carbon-14 has 6 protons and 8 neutrons.

Common mistakes

✗ Forgetting to mention the number of protons is the same. ✗ Mentioning electrons - the number of electrons is the same in neutral atoms of isotopes, but the defining feature relates to the nucleus. ✗ Saying "different mass number" without explaining that this is due to a different number of neutrons.

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