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AQA GCSE · Question 09.2 · Chemical changes
Explain what happens to the pH of an acid as the acid is diluted with water.
Explain what happens to the pH of an acid as the acid is diluted with water.
How to approach this question
1. What does diluting an acid with water do to the concentration of H⁺ ions?
2. How is pH related to the concentration of H⁺ ions? (A lower H⁺ concentration means...?)
3. Combine these two points to explain the effect on pH.
Full Answer
The pH of the acid increases (becomes less acidic). This is because dilution decreases the concentration of H⁺ ions in the solution.
The pH scale is a measure of the concentration of hydrogen ions (H⁺) in a solution. A lower pH indicates a higher concentration of H⁺ ions (more acidic), while a higher pH indicates a lower concentration of H⁺ ions (less acidic).
When an acid is diluted by adding water, the total number of H⁺ ions remains the same, but the total volume of the solution increases. This causes the concentration of H⁺ ions (moles per unit volume) to decrease.
Because the concentration of H⁺ ions has decreased, the solution becomes less acidic, and its pH value increases, moving closer to the neutral pH of 7.
Common mistakes
✗ Saying "the pH decreases" - this would mean it becomes more acidic.
✗ Saying "it becomes neutral" - it only approaches neutral, it doesn't become it unless an infinite amount of water is added.
✗ Not mentioning the concentration of H⁺ ions.
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