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    PracticeAQA GCSEAQA GCSE Chemistry Higher Tier Paper 1Question 09.5
    Hard3 marksStructured
    Atomic structure and the periodic tableHigherreactivitygroup 2atomic structure

    AQA GCSE · Question 09.5 · Atomic structure and the periodic table

    A calcium atom is larger than a magnesium atom.
    Explain why calcium reacts more vigorously than magnesium with hydrochloric acid of the same concentration.

    How to approach this question

    This question is about the trend in reactivity down Group 2. 1. **Electron Shells:** Calcium is below magnesium in Group 2. How does this affect the distance of the outer electrons from the nucleus? 2. **Shielding:** How does the number of inner electron shells affect the attraction between the nucleus and the outer electrons? 3. **Ease of Electron Loss:** How do distance and shielding affect how easily the atom can lose its outer electrons to react? 4. **Reactivity:** Relate the ease of electron loss to the reactivity of the metal.

    Full Answer

    Calcium and magnesium are in Group 2. Reactivity increases down the group. The outer electrons of a calcium atom are further from the nucleus than in a magnesium atom. Therefore, the outer electrons in calcium are more shielded from the nuclear charge and experience a weaker electrostatic attraction to the nucleus. This means it is easier for a calcium atom to lose its two outer electrons, making it more reactive.
    Magnesium (Mg) and Calcium (Ca) are both in Group 2 of the periodic table. When they react, they lose their two outer shell electrons. The reactivity of Group 2 metals increases down the group. The explanation involves three factors: 1. **Atomic Radius:** A calcium atom is larger than a magnesium atom. This means its outermost electrons are in a higher energy level (shell 4 for Ca vs. shell 3 for Mg) and are further away from the positive nucleus. 2. **Shielding:** A calcium atom has more inner shells of electrons than a magnesium atom. These inner electrons "shield" the outer electrons from the full attractive force of the positive nucleus. 3. **Nuclear Attraction:** Due to the greater distance and increased shielding effect, the electrostatic force of attraction between the nucleus and the two outer electrons is weaker in a calcium atom compared to a magnesium atom. Because the outer electrons are held less strongly, less energy is required to remove them. Therefore, calcium loses its electrons more easily and reacts more vigorously than magnesium.

    Common mistakes

    ✗ Just stating "reactivity increases down the group" without explaining why. ✗ Confusing the trend with Group 7 (where reactivity decreases down the group). ✗ Not mentioning electron shielding.
    Question 09.4All questions

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