Medium2 marksStructured
The rate and extent of chemical changeHigherindustrial chemistrycompromise conditions

AQA GCSE · Question 07.4 · The rate and extent of chemical change

In industry, the reaction is done at 450 °C and atmospheric pressure. Under these conditions the yield of sulfur trioxide is 86%.
Suggest two reasons why a higher pressure is not used.

How to approach this question

We know from the previous question that a higher pressure would increase the yield. So why don't industrial processes use extremely high pressures? Think about the practical and economic challenges of creating and containing high-pressure systems.

Full Answer

Any two from: - High pressures are expensive to generate and maintain, as they require a lot of energy for the pumps. - Building and maintaining equipment (pipes, reactor) that can withstand very high pressures is very expensive and difficult. - There is a safety risk associated with operating at very high pressures.
Industrial chemical processes are always a compromise between factors that affect the rate of reaction, the percentage yield, and the cost. While Le Chatelier's principle tells us that a high pressure would favour a higher yield of sulfur trioxide, there are significant economic and safety reasons for not using excessively high pressures. 1. **Cost of Energy:** Compressing gases to high pressures requires powerful pumps, which consume large amounts of electrical energy. This adds a significant operational cost to the process. 2. **Cost of Equipment:** The reactor, pipes, and valves must be built to be extremely strong and durable to safely contain gases at high pressure. This requires thick steel and specialised engineering, making the plant very expensive to build and maintain. 3. **Safety:** Operating at high pressures increases the risk of explosions or leaks if the equipment fails. While safety systems are in place, lower pressures are inherently safer. Therefore, a compromise pressure is used that gives a reasonably high yield and rate without making the process prohibitively expensive or dangerous.

Common mistakes

✗ Giving reasons related to the yield or rate (the question states higher pressure *would* be better for yield). ✗ Giving only one reason. ✗ Vague answers like "it's too expensive" without specifying what is expensive (energy, equipment).

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