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Organic chemistryHigherorganic chemistryalkenesaddition reaction

AQA GCSE · Question 08.2 · Organic chemistry

Describe what will be seen when compound A is shaken with bromine water.

How to approach this question

This question asks for the test for an alkene. Compound A has a C=C double bond. 1. What is the standard chemical test for unsaturation (the presence of a C=C double bond)? It involves bromine water. 2. What is the initial colour of bromine water? 3. What is the final colour after a positive reaction with an alkene?

Full Answer

The bromine water will be decolourised / turn from orange/brown/yellow to colourless.
The test for an alkene (a compound containing a C=C double bond) is to shake it with bromine water. Bromine water is an aqueous solution of bromine, which has a distinct orange-brown or yellow colour. Alkenes undergo an addition reaction with bromine, where the double bond breaks and a bromine atom adds to each of the two carbon atoms. The product, a dibromoalkane, is colourless. Because the bromine is used up in the reaction, its colour disappears. Therefore, a positive test for an alkene is that the orange/brown/yellow bromine water is decolourised (turns colourless).

Common mistakes

✗ Just saying "it changes colour" without specifying the start and end colours. ✗ Getting the colours wrong. ✗ Confusing the test with the test for other functional groups.

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