Medium2 marksMultiple Choice
The rate and extent of chemical changeFoundationcollision theoryconcentrationrates of reaction

AQA GCSE · Question 07.7 · The rate and extent of chemical change

The student concludes that the rate of reaction is greater when the concentration of hydrochloric acid is higher. Why is the rate of reaction greater when the concentration of hydrochloric acid is higher? Select two options.

Answer options:

A.

The particles are moving faster

B.

The particles have more energy

C.

The surface area of magnesium is smaller

D.

There are more particle collisions each second

E.

There are more particles in the same volume

How to approach this question

This question is about collision theory and the effect of concentration. 1. What does "higher concentration" mean in terms of particles in a given space? 2. If there are more particles in the same space, what will happen to the number of times they collide with each other? 3. How does the frequency of collisions affect the reaction rate? 4. Consider the other options. What factor affects particle speed and energy? (Temperature). What factor is surface area related to? (The solid reactant).

Full Answer

There are more particle collisions each second, There are more particles in the same volume
According to collision theory, for a reaction to occur, reactant particles must collide with sufficient energy. The rate of reaction depends on the frequency of these successful collisions. - **Higher concentration** means that there are **more reactant particles in the same volume**. (This is the definition of concentration). - Because the particles are more crowded, they will collide with each other and with the magnesium more often. This means **there are more particle collisions each second** (an increased frequency of collisions). - An increased frequency of collisions leads to an increased frequency of successful collisions, and therefore a faster rate of reaction. - The speed and energy of the particles are determined by the temperature, which is a control variable in this experiment.

Common mistakes

✗ Confusing the effect of concentration with the effect of temperature (which affects particle energy and speed). ✗ Selecting only one of the two correct, linked statements.

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